chkconfig is a command available in CentOS 6 to set a service start on boot.
To start lighttpd on boot run.
chkconfig --levels 235 lighttpd on
chkconfig command list all services and its run levels.
[root@server12 ~]# chkconfig acpid 0:off 1:off 2:on 3:on 4:on 5:on 6:off atd 0:off 1:off 2:off 3:on 4:on 5:on 6:off auditd 0:off 1:off 2:on 3:on 4:on 5:on 6:off blk-availability 0:off 1:on 2:on 3:on 4:on 5:on 6:off cgconfig 0:off 1:off 2:on 3:on 4:on 5:on 6:off cgred 0:off 1:off 2:off 3:off 4:off 5:off 6:off crond 0:off 1:off 2:on 3:on 4:on 5:on 6:off csf 0:off 1:off 2:on 3:on 4:on 5:on 6:off dnsmasq 0:off 1:off 2:off 3:off 4:off 5:off 6:off docker 0:off 1:off 2:on 3:on 4:on 5:on 6:off ebtables 0:off 1:off 2:off 3:off 4:off 5:off 6:off exim 0:off 1:off 2:on 3:on 4:on 5:on 6:off haldaemon 0:off 1:off 2:off 3:on 4:on 5:on 6:off htcacheclean 0:off 1:off 2:off 3:off 4:off 5:off 6:off httpd 0:off 1:off 2:on 3:on 4:on 5:on 6:off ip6tables 0:off 1:off 2:on 3:on 4:on 5:on 6:off iptables 0:off 1:off 2:off 3:off 4:off 5:off 6:off iscsi 0:off 1:off 2:off 3:on 4:on 5:on 6:off iscsid 0:off 1:off 2:off 3:on 4:on 5:on 6:off lfd 0:off 1:off 2:on 3:on 4:on 5:on 6:off lvm2-monitor 0:off 1:on 2:on 3:on 4:on 5:on 6:off lxc 0:off 1:off 2:off 3:off 4:off 5:off 6:off mdmonitor 0:off 1:off 2:on 3:on 4:on 5:on 6:off messagebus 0:off 1:off 2:on 3:on 4:on 5:on 6:off mysqld 0:off 1:off 2:on 3:on 4:on 5:on 6:off netcf-transaction 0:off 1:off 2:on 3:on 4:on 5:on 6:off netconsole 0:off 1:off 2:off 3:off 4:off 5:off 6:off netfs 0:off 1:off 2:off 3:on 4:on 5:on 6:off network 0:off 1:off 2:on 3:on 4:on 5:on 6:off newrelic-sysmond 0:off 1:off 2:on 3:on 4:on 5:on 6:off nginx 0:off 1:off 2:on 3:on 4:on 5:on 6:off ntpd 0:off 1:off 2:off 3:off 4:off 5:off 6:off ntpdate 0:off 1:off 2:off 3:off 4:off 5:off 6:off numad 0:off 1:off 2:off 3:off 4:off 5:off 6:off pure-ftpd 0:off 1:off 2:on 3:on 4:on 5:on 6:off radvd 0:off 1:off 2:off 3:off 4:off 5:off 6:off rdisc 0:off 1:off 2:off 3:off 4:off 5:off 6:off redmine 0:off 1:off 2:on 3:on 4:on 5:on 6:off restorecond 0:off 1:off 2:off 3:off 4:off 5:off 6:off rsyslog 0:off 1:off 2:on 3:on 4:on 5:on 6:off saslauthd 0:off 1:off 2:off 3:off 4:off 5:off 6:off smartd 0:off 1:off 2:off 3:off 4:off 5:off 6:off sshd 0:off 1:off 2:on 3:on 4:on 5:on 6:off svnserve 0:off 1:off 2:off 3:off 4:off 5:off 6:off sysstat 0:off 1:on 2:on 3:on 4:on 5:on 6:off udev-post 0:off 1:on 2:on 3:on 4:on 5:on 6:off vnstat 0:off 1:off 2:on 3:on 4:on 5:on 6:off yum-cron 0:off 1:off 2:on 3:on 4:on 5:on 6:off [root@server12 ~]#